HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ammonium Chloride → (5-Allyloxy-2-nitro-phenyl)-(4-isopropyl-phenyl)-methanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ammonium Chloride | HCID 25517 | — |
| Reactant | Sodium Bisulfite | HCID 23665763 | — |
| Reactant | (5-Allyloxy-2-nitro-phenyl)-(4-isopropyl-phenyl)-methanol | HCID 59259038 | — |
| Reactant | Jones' reagent | HCID 131709961 | — |
| Solvent | Acetone | HCID 180 | — |
| Solvent | Isopropanol | HCID 3776 | — |
| Product | (5-Allyloxy-2-nitro-phenyl)-(4-isopropyl-phenyl)-methanone | HCID 59259161 | — |
Reaction Steps
A solution of 16.38 g (50 mmol) (5-allyloxy-2-nitro-phenyl)-(4-isopropyl-phenyl)-methanol in 60 ml acetone is treated at 0° C. with 20 ml (53.4 mmol) Jones reagent. After stirring for 2 h at r.t. isopropanol, an aqueous solution of sodium bisulphite and saturated aqueous ammonium chloride solution are added. Extraction with dichloromethane affords (5-allyloxy-2-nitro-phenyl)-(4-isopropyl-phenyl)-methanone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07696216B2 |
| Source dataset | uspto-grants-2010_04 |
| ORD ID | ord-03e93b81e63e4013a399e0a889ea7a7f |
| Source note | uspto-grants-2010_04 |