HCID 86617366, compound → HCID 68428157, compound

HRID 642427Notes

Reaction equation

HRID 642427 reaction equation
[CH2:1]([O:3][C:4]([C:6]1[N:18]=[C:17](Br)[C:16]2[C:15]3[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=3[N:9]([C:20]3[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=3)[C:8]=2[C:7]=1[OH:26])=[O:5])[CH3:2].[C:27]([Cu])#[N:28]>>[CH2:1]([O:3][C:4]([C:6]1[N:18]=[C:17]([C:27]#[N:28])[C:16]2[C:15]3[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=3[N:9]([C:20]3[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=3)[C:8]=2[C:7]=1[OH:26])=[O:5])[CH3:2]

Participants

3

Reactant 2

HCID 86617366HCID 86617366, compoundHCID 178418546HCID 178418546, compound

Product 1

HCID 68428157HCID 68428157, compound

Procedure

Prepared in analogy to that of Example 105(a) from 1-bromo-4-hydroxy-5-phenyl-5H-pyrido[4,3-b]indole-3-carboxylic acid ethyl ester and CuCN. The title compound, ESI MS (m/z): 358 (M+H)+.

Sources & evidence

ORD record
ord-f8f2284c94f043d6b18f8fd3c9d7204d
Source dataset
uspto-grants-2010_04
Patent number
US07696223B2

Reaction notes

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