HCID 86617376, compound → HCID 68428665, compound

HRID 642525Notes

Reaction equation

HRID 642525 reaction equation
[CH2:1]([O:3][C:4]([C:6]1[C:7]([OH:27])=[C:8]2[C:15]([Br:16])=[C:14]([Br:17])[N:13]([CH2:18][C:19]3[CH:24]=[CH:23][CH:22]=[C:21]([O:25][CH3:26])[CH:20]=3)[C:9]2=[C:10](Br)[N:11]=1)=[O:5])[CH3:2].[C:28]([Cu])#[N:29]>>[CH2:1]([O:3][C:4]([C:6]1[C:7]([OH:27])=[C:8]2[C:15]([Br:16])=[C:14]([Br:17])[N:13]([CH2:18][C:19]3[CH:24]=[CH:23][CH:22]=[C:21]([O:25][CH3:26])[CH:20]=3)[C:9]2=[C:10]([C:28]#[N:29])[N:11]=1)=[O:5])[CH3:2]

Participants

3

Reactant 2

HCID 86617376HCID 86617376, compoundHCID 178418546HCID 178418546, compound

Product 1

HCID 68428665HCID 68428665, compound

Procedure

Prepared in analogy to that of Example 105(a) from 2,3,7-tribromo-1-(3-methoxy-benzyl)-4-hydroxy-1H-pyrrolo[2,3-c]pyridine-5-carboxylic acid ethyl ester and CuCN. The title compound, ESI MS (m/z): 508 (M+H)+.

Sources & evidence

ORD record
ord-7108a74725704080beb0bbd3dce0790a
Source dataset
uspto-grants-2010_04
Patent number
US07696223B2

Reaction notes

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