o-Chloranil → HCID 68577865, compound

HRID 642658Notes

Reaction equation

[CH:1]([O:4][C:5]1[CH:14]=[C:13]2[C:8]([C:9]([CH3:15])=[CH:10][CH2:11][CH2:12]2)=[CH:7][CH:6]=1)([CH3:3])[CH3:2].ClC1C(=O)C(=O)C(Cl)=C(Cl)C=1Cl>>[CH:1]([O:4][C:5]1[CH:14]=[C:13]2[C:8](=[CH:7][CH:6]=1)[C:9]([CH3:15])=[CH:10][CH:11]=[CH:12]2)([CH3:3])[CH3:2]

Participants

Reactant 2

HCID 73252o-Chloranil

HCID 68578523HCID 68578523, compound

Product 1

HCID 68577865HCID 68577865, compound

Procedure

Using general procedure A (Exp. 1.2.), 7-isopropoxy-4-methyl-1,2-dihydro-naphthalene was reacted with 3,4,5,6-tetrachloro-1,2-benzoquinone to give 6-isopropoxy-1-methyl-naphthalene as a pale yellow oil. MS: 201.3 ([M+H]+).

Sources & evidence

ORD record: ord-2211d1f81a7c4d05abd1f2941c462631
Source dataset: uspto-grants-2010_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07696240B2

Reaction notes

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