2,2-Dimethylpent-4-en-1-ol → Benzoic acid 6-(5-hydroxy-4,4-dimethylpentyl)-3-(1,1,4-trioxo-1,2,5-thiadiazolidin-2-yl)-naphthalen-2-yl ester

HRID 643897Notes

Reaction equation

HRID 643897 reaction equation
Br[C:2]1[CH:3]=[C:4]2[C:9](=[CH:10][CH:11]=1)[CH:8]=[C:7]([O:12][C:13](=[O:20])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)[C:6]([N:21]1[CH2:25][C:24](=[O:26])[NH:23][S:22]1(=[O:28])=[O:27])=[CH:5]2.[CH3:29][C:30]([CH3:36])([CH2:33][CH:34]=[CH2:35])[CH2:31][OH:32]>>[OH:32][CH2:31][C:30]([CH3:36])([CH3:29])[CH2:33][CH2:34][CH2:35][C:2]1[CH:3]=[C:4]2[C:9](=[CH:10][CH:11]=1)[CH:8]=[C:7]([O:12][C:13](=[O:20])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)[C:6]([N:21]1[CH2:25][C:24](=[O:26])[NH:23][S:22]1(=[O:27])=[O:28])=[CH:5]2

Participants

3

Reactant 2

HCID 107491582,2-Dimethylpent-4-en-1-olHCID 86624016Benzoic acid 6-bromo-3-(1,1,4-trioxo-1,2,5-thiadiazolidin-2-yl)-naphthalen-2-yl ester

Product 1

HCID 17751433Benzoic acid 6-(5-hydroxy-4,4-dimethylpentyl)-3-(1,1,4-trioxo-1,2,5-thiadiazolidin-2-yl)-naphthalen-2-yl ester

Procedure

The title compound is prepared analogously to Example 8, step A, from benzoic acid 6-bromo-3-(1,1,4-trioxo-1,2,5-thiadiazolidin-2-yl)-naphthalen-2-yl ester and 2,2-dimethylpent-4-en-1-ol: Retention time=1.30 min (Method A); (M−H)−=495.

Sources & evidence

ORD record
ord-796102112d3b43ef8661aa528f075cb9
Source dataset
uspto-grants-2010_04
Patent number
US07700633B2

Reaction notes

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