Aluminium lithium hydride → HCID 68579522, compound

HRID 644571Notes

Reaction equation

HRID 644571 reaction equation
[Si:1]([O:8][C:9]1[CH:10]=[C:11](/[C:15](/[CH2:22][CH3:23])=[CH:16]/[C:17](OCC)=[O:18])[CH:12]=[CH:13][CH:14]=1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2].[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[Si:1]([O:8][C:9]1[CH:10]=[C:11](/[C:15](/[CH2:22][CH3:23])=[CH:16]/[CH2:17][OH:18])[CH:12]=[CH:13][CH:14]=1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:2])[CH3:3]

Participants

3

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 86761083HCID 86761083, compound

Product 1

HCID 68579522HCID 68579522, compound

Procedure

In a manner analogous to example 1e, by reaction of 7.6 g (23 mmol) of ethyl (E)-3-[3-(tert-butyldimethylsilanyloxy)phenyl]pent-2-enoate with 1.05 g (25 mmol) of lithium aluminum hydride. A colorless oil is obtained (m=6.7 g; Y=100%).

Workup

  1. customA colorless oil is obtained (m=6.7 g; Y=100%)

Sources & evidence

ORD record
ord-f8e6e0e7f7564f1487340894c428b325
Source dataset
uspto-grants-2010_04
Patent number
US07700657B2

Reaction notes

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