HCID 68579522, compound → HCID 86761084, compound

HRID 644572Notes

Reaction equation

HRID 644572 reaction equation
[Si:1]([O:8][C:9]1[CH:10]=[C:11](/[C:15](/[CH2:19][CH3:20])=[CH:16]/[CH2:17][OH:18])[CH:12]=[CH:13][CH:14]=1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2]>[O-2].[O-2].[Mn+4]>[Si:1]([O:8][C:9]1[CH:10]=[C:11](/[C:15](/[CH2:19][CH3:20])=[CH:16]/[CH:17]=[O:18])[CH:12]=[CH:13][CH:14]=1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:2])[CH3:3]

Participants

3

Reactant 1

HCID 68579522HCID 68579522, compound

Product 1

HCID 86761084HCID 86761084, compound

Reagents, catalysts & solvents 1

HCID 178418406HCID 178418406, compoundCatalyst

Procedure

In a manner analogous to example 1j, by reaction of 6.7 g (23 mmol) of (E)-3-[3-(tert-butyldimethylsilanyloxy)phenyl]pent-2-en-1-ol with 10 g (115 mmol) of manganese dioxide. A yellow oil is obtained (m=4.7 g; Y=71%).

Workup

  1. customA yellow oil is obtained (m=4.7 g; Y=71%)

Sources & evidence

ORD record
ord-632b060dc8e24b778a9954a0652b4aaa
Source dataset
uspto-grants-2010_04
Patent number
US07700657B2

Reaction notes

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