HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 17829551, compound → HCID 68421412, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 17829551 | HCID 17829551 | — |
| Reactant | HCID 67458210 | HCID 67458210 | — |
| Catalyst | HCID 178418397 | HCID 178418397 | — |
| Solvent | Toluene water | HCID 22272177 | — |
| Product | HCID 68421412 | HCID 68421412 | 54.1% |
Reaction Steps
Under argon atmosphere and in a toluene/water mixed solvent, 6-bromonaphthalene-1,4-dicarboxylic-acid diethyl ester 4.5 g and 4-(3,7-dimethyloctyloxy)phenyl boric acid 4.0 g were reacted with using tetrakis(triphenylphosphine)palladium under a condition of usual Suzuki reaction. Purification by column treatment (silica gel/toluene) was carried out, and 6-(4-(3,7-dimethyloctyloxy)phenyl)naphthalene-1,4-dicarboxylic-acid diethyl ester 3.5 g was obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07701129B2 |
| Source dataset | uspto-grants-2010_04 |
| ORD ID | ord-b3c2873fdb8a4c02b586e8cc08ea603d |
| Source note | uspto-grants-2010_04 |