HCID 11118006, compound → HCID 17829549, compound

HRID 645311Notes

Reaction equation

C(OC(C1C2C(=CC([C:16]3[CH:21]=[CH:20][C:19]([O:22][CH2:23][CH2:24][CH:25]([CH3:32])[CH2:26][CH2:27][CH2:28][CH:29]([CH3:31])[CH3:30])=[CH:18][CH:17]=3)=CC=2)C(C(OCC)=O)=CC=1)=O)C.[CH3:38][C:39]1[C:48]2[C:43](=[CH:44][CH:45]=[CH:46][CH:47]=2)[C:42]([CH3:49])=[CH:41][C:40]=1Br>>[CH3:38][C:39]1[C:48]2[C:43](=[CH:44][CH:45]=[CH:46][CH:47]=2)[C:42]([CH3:49])=[CH:41][C:40]=1[C:16]1[CH:21]=[CH:20][C:19]([O:22][CH2:23][CH2:24][CH:25]([CH3:32])[CH2:26][CH2:27][CH2:28][CH:29]([CH3:31])[CH3:30])=[CH:18][CH:17]=1

Participants

Reactant 2

HCID 11118006HCID 11118006, compound

HCID 68421412HCID 68421412, compound

Product 1

HCID 17829549HCID 17829549, compound

Procedure

1,4-dimethyl-2-(4-(3,7-dimethyloctyloxy)phenyl)naphthalene was prepared in accordance with the case of 6-(4-(3,7-dimethyloctyloxy)phenyl)naphthalene-1,4-dicarboxylic-acid diethyl ester described above, but using 1,4-dimethyl-2-bromonaphthalene, as a raw material, which was obtained by brominating 1,4-dimethylnaphtalene with Br2. 1,4-dimethyl-2-(4-(3,7-dimethyloctyloxy)phenyl)naphthalene was dissolved in carbon tetrachloride, and reacted to NBS to obtain 1,4-bis(bromomethyl)-2-{4-(3,7-dimethyloctyloxy)phenyl}naphthalene was obtained.

Workup

customas a raw material, which was obtained

Sources & evidence

ORD record: ord-0ee7da15697c4d4da4f978b7a6ee6335
Source dataset: uspto-grants-2010_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07701129B2

Reaction notes

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