HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → 4-Chloro-1-(4-chloro-2-methylphenoxy)-2-butanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 4-Chloro-2-methylphenol | HCID 14855 | — |
| Reactant | 1,4-Dichloro-2-butanol | HCID 17021 | — |
| Solvent | tert-Butanol | HCID 6386 | — |
| Product | 4-Chloro-1-(4-chloro-2-methylphenoxy)-2-butanol | HCID 13120346 | — |
Reaction Steps
4-Chloro-1-(4-chloro-2-methylphenoxy)-2-butanol was prepared according to the procedure of Preparation 4 using 105 g. (0.74 mole) of 2-methyl-4-chlorophenol, 171.5 g. (1.2 mole) of 1,4-dichloro-2-butanol, 50.3 g. of sodium hydroxide, 300 ml. of water and 300 ml. of tertiary butanol. There was obtained 84 g. (45.5%) of product which distilled at 135° C./0.01 mm.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04609735 |
| Source dataset | uspto-grants-1986_09 |
| ORD ID | ord-008d879749ca4fe7974966c270b01e5d |
| Source note | uspto-grants-1986_09 |