Ethyl propiolate → 1-(3-Oxoprop-1-en-1-yl)aziridine-2-carbonitrile

HRID 647524Notes

Reaction equation

HRID 647524 reaction equation
C(OCC)(=O)C#C.[C:8]([CH:10]1[CH2:12][N:11]1[CH:13]=[CH:14][C:15](OCC)=[O:16])#[N:9]>>[C:8]([CH:10]1[CH2:12][N:11]1[CH:13]=[CH:14][CH:15]=[O:16])#[N:9]

Participants

3

Reactant 2

HCID 12182Ethyl propiolateHCID 53727000Ethyl 3-(2-cyanoaziridin-1-yl)prop-2-enoate

Product 1

HCID 542879171-(3-Oxoprop-1-en-1-yl)aziridine-2-carbonitrileYield 24%

Procedure

ethyl propiolate: ethyl 3-(2-cyanoaziridin-1-yl)-acrylate; oily substance, purified with a silica gel column; yield 24% of theory.

Workup

  1. customoily substance, purified with a silica gel column

Sources & evidence

ORD record
ord-ea0ad15e152c4177a36da403c9c9457d
Source dataset
uspto-grants-1983_10
Patent number
US04409236

Reaction notes

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