HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methomyl → Methyl N-[[[[[(diethoxyphosphinothioyl)isopropylamino]sulfinyl]methylamino]carbonyl]oxy]ethanimidothioate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methomyl | HCID 4109 | — |
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | Phosphoramidothioic acid, (1-methylethyl)-, O,O-diethyl ester | HCID 778771 | — |
| Solvent | Pyridine | HCID 1049 | — |
| Product | Methyl N-[[[[[(diethoxyphosphinothioyl)isopropylamino]sulfinyl]methylamino]carbonyl]oxy]ethanimidothioate | HCID 86739075 | — |
Reaction Steps
Methyl N-[[[[[(diethoxyphosphinothioyl)isopropylamino]sulfinyl]methylamino]carbonyl]oxy]ethanimidothioate was prepared by the procedure employed in Example 9, by reacting methyl N-[[(methylamino)carbonyl]oxy]ethanimidothioate (2.43 g, 0.015 mole), thionyl chloride (1.79 g, 0.015 mole), and O,O-diethyl isopropylphosphoramidothioate (3.17 g, 0.015 mole) in pyridine (10 ml). Recrystallization from cyclohexane afforded 1.73 g of colorless prisms of the formula below, mp 53~54°. ##STR27##
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04410518 |
| Source dataset | uspto-grants-1983_10 |
| ORD ID | ord-3e83de3531d44c178b3cdf45483ba5d4 |
| Source note | uspto-grants-1983_10 |