Methomyl → HCID 86739077, compound

HRID 647792Notes

Reaction equation

HRID 647792 reaction equation
[CH3:1][NH:2][C:3]([O:5][N:6]=[C:7]([S:9][CH3:10])[CH3:8])=[O:4].[S:11](Cl)(Cl)=[O:12].[CH:15]1([NH:21][P:22](=[S:29])([O:26][CH2:27][CH3:28])[O:23][CH2:24][CH3:25])[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16]1>N1C=CC=CC=1>[CH2:24]([O:23][P:22]([N:21]([CH:15]1[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16]1)[S:11]([CH2:1][NH:2][C:3]([O:5][N:6]=[C:7]([S:9][CH3:10])[CH3:8])=[O:4])=[O:12])([O:26][CH2:27][CH3:28])=[S:29])[CH3:25]

Participants

5

Reactant 3

HCID 4109MethomylHCID 24386Thionyl ChlorideHCID 12943052HCID 12943052, compound

Product 1

HCID 86739077HCID 86739077, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

Methyl N-[[[[[(diethoxyphosphinothioyl)cyclohexylamino]sulfinyl]methylamino]carbonyl]oxy]ethanimidothioate was prepared by the procedure employed in Example 9, by reacting methyl N-[[(methylamino)carbonyl]oxy]ethanimidothioate (2.43 g, 0.015 mole), thionyl chloride (1.79 g, 0.015 mole) and O,O-diethyl cyclohexylphosphoramidothioate (3.77 g, 0.015 mole) in pyridine 10 ml. Recrystallization from chloroform-hexane afforded 2.5 g of colorless prisms of the formula below, mp 72~74°. ##STR31##

Workup

  1. customRecrystallization from chloroform-hexane

Sources & evidence

ORD record
ord-904fe0721fc049a4b8ac6d2da67dd234
Source dataset
uspto-grants-1983_10
Patent number
US04410518

Reaction notes

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