HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methomyl → HCID 86739079, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methomyl | HCID 4109 | — |
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | 2-(Ethylamino)-5,5-dimethyl-1,3,2lambda~5~-dioxaphosphinane-2-thione | HCID 20483150 | — |
| Solvent | Pyridine | HCID 1049 | — |
| Product | HCID 86739079 | HCID 86739079 | — |
Reaction Steps
Methyl N-[[[[[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)(ethyl)amino]sulfinyl]methylamino]carbonyl]oxy]ethanimidothioate was prepared by the procedure employed in Example 9, by reacting methyl N-[[(methylamino)carbonyl]oxy]ethanimidothioate (2.43 g, 0.015 mole), thionyl chloride (1.79 g, 0.015 mole), and 5,5-dimethyl-2-ethylamino-2-thioxo-1,3,2-dioxaphosphorinan (3.14 g, 0.015 mole) in pyridine (10 ml). Recrystallization from chloroform-hexane afforded 2.2 g of needles of the formula below, mp 136~138°. ##STR36##
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04410518 |
| Source dataset | uspto-grants-1983_10 |
| ORD ID | ord-490e200822a04061b7fe5217d3d648d4 |
| Source note | uspto-grants-1983_10 |