HCID 12507348, compound → HCID 57108974, compound

HRID 648668Notes

Reaction equation

HRID 648668 reaction equation
ClC1(Cl)[C@@H]2[C@@H](CCC=C2)C1=O.[CH3:12][O:13][C@@:14]12[C:21](=[O:22])[CH2:20][C@@H:19]1[CH:18]=[CH:17][CH2:16][CH2:15]2>>[CH3:12][O:13][C@:14]12[C:21](=[O:22])[CH2:20][C@H:19]1[CH:18]=[CH:17][CH2:16][CH2:15]2

Participants

3

Reactant 2

HCID 12507348HCID 12507348, compoundHCID 54568732HCID 54568732, compound

Product 1

HCID 57108974HCID 57108974, compound

Procedure

Similarly, starting with (1S,6R)-8,8-dichlorobicyclo[4.2.0]oct-2-en-7-one, prepared as shown in Preparation 22, in place of the racemic compound in Preparation 2.A. above, (1S,6S)-6-methoxybicyclo[4.2.0]oct-2-en-7-one is prepared. Similarly, starting with the (1R,6S)-compound, (1R,6R)-6-methoxybicyclo[4.2.0]oct-2-en-7-one is prepared.

Workup

  1. customprepared
  2. customis prepared

Sources & evidence

ORD record
ord-9f4beee2f2f84700a3a08c5e3b52f36a
Source dataset
uspto-grants-1988_04
Patent number
US04735966

Reaction notes

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