Acetic Acid → HCID 53962828, compound

HRID 648810Notes

Reaction equation

HRID 648810 reaction equation
[NH2:1][C:2]1[C:7]([CH3:8])=[C:6]([CH3:9])[C:5]([NH:10][C:11](=O)OCCCl)=[CH:4][C:3]=1[N+:17]([O-:19])=[O:18].[OH-].[Na+].[C:22](O)(=[O:24])C>O>[NH2:1][C:2]1[C:7]([CH3:8])=[C:6]([CH3:9])[C:5]([NH:10][CH2:11][CH2:22][OH:24])=[CH:4][C:3]=1[N+:17]([O-:19])=[O:18]

Participants

5

Reactant 3

HCID 176Acetic AcidHCID 14798Sodium HydroxideHCID 20145996HCID 20145996, compound

Product 1

HCID 53962828HCID 53962828, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

0.0417 mole (12 g) of β-chloroethyl 4-amino-5,6-dimethyl-3-nitrophenylcarbamate is suspended in 36 ml of 96° alcohol. A solution of 6.2 g of caustic soda pellets of 97% strength in 15 ml of water is added in small portions with stirring; the reaction mixture is heated to the refluxing temperature of the alcohol. After being heated for 2 hours the reaction mixture is poured into 200 g of iced water and acidified with acetic acid.

Workup

  1. temperatureAfter being heated for 2 hours the reaction mixture

Sources & evidence

ORD record
ord-c15680e8204442e39efc387c746ee25e
Source dataset
uspto-grants-1988_04
Patent number
US04736067

Reaction notes

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