Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetone → N-(1,3-dithiol-2-ylidene)-N-methyl-N-(3-methylthio-1-ethoxycarbonylpropyl)ammonium perchlorate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetone | HCID 180 | — |
| 반응물 | Diethyl Ether | HCID 3283 | — |
| 반응물 | 2-Methylthio-1,3-dithiolium perchlorate | HCID 23039009 | — |
| 반응물 | Ethyl methyl-L-methioninate | HCID 54331404 | — |
| 용매 | Ethyl Acetate | HCID 8857 | — |
| 생성물 | N-(1,3-dithiol-2-ylidene)-N-methyl-N-(3-methylthio-1-ethoxycarbonylpropyl)ammonium perchlorate | HCID 20144146 | 222.1% |
반응 단계
To 100 ml of acetone, 2.0 g of 2-methylthio-1,3-dithiolium perchlorate was dissolved, and 50 ml of an ethyl ether solution containing 2.3 g of N-methyl methionine ethyl ester was gradually added thereto under stirring at room temperature. The mixture was stirred at room temperature for 6 hours, and then the solvent was distilled off. The residue was washed with ethyl acetate, whereby 7 g (yield: 54%) of N-(1,3-dithiol-2-ylidene)-N-methyl-N-(3-methylthio-1-ethoxycarbonylpropyl)ammonium perchlorate (Compound No. 6) was obtained as oily substance.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04737494 |
| 출처 데이터셋 | uspto-grants-1988_04 |
| ORD ID | ord-def2b37d134847c1a77ea87029718266 |
| 출처 메모 | uspto-grants-1988_04 |