HuagongsheHuagongshe Chemistry Print Report · For research reference only
Azepane → 1-(1,3-Dithiol-2-ylidene)hexahydroazepinium perchlorate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Azepane | HCID 8119 | — |
| Reactant | 2-Methylthio-1,3-dithiolium perchlorate | HCID 23039009 | — |
| Solvent | Acetone diethylether | HCID 21584533 | — |
| Product | 1-(1,3-Dithiol-2-ylidene)hexahydroazepinium perchlorate | HCID 13654966 | 52% |
Reaction Steps
0.25 g of hexahydroazepine and 0.5 g of 2-methylthio-1,3-dithiolium perchlorate were teated in the same manner as in Example 26, and the product was recrystallized from acetone-ethyl ether, whereby 0.31 g (yield: 52.0%) of 1-(1,3-dithiol-2-ylidene)hexahydroazepinium perchlorate (Compound No. 37) was obtained as crystals having a melting point of from 86° to 88° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04737494 |
| Source dataset | uspto-grants-1988_04 |
| ORD ID | ord-3c70cb5883f74c8d81abfcf71332d5fc |
| Source note | uspto-grants-1988_04 |