2-Methylpiperidine → HCID 14127461, compound

Participants

Reaction Steps

To 50 ml of tetrahydrofuran, 1.1 g of α-pipecoline was dissolved, and 2.0 g of 2-methylthio-1,3-dithiolium perchlorate was gradually added thereto under stirring at room temperature. The mixture was stirred at room temperature for 1 hour, and then 50 ml of ethyl ether was added thereto, whereby 1.5 g (yield: 80%) of 1-(1,3-dithiol-2-ylidene)-2-methylpiperidinium perchlorate (Compound No. 51) was obtained as yellow oily precipitates.

Provenance & Evidence