HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 12496209, compound → HCID 13755170, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 12496209 | HCID 12496209 | — |
| Reactant | [1-(Prop-2-yn-1-yl)-2-(trifluoromethyl)-1H-pyrrol-3-yl]methanol | HCID 13605020 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 13755170 | HCID 13755170 | 99.9% |
Reaction Steps
Using the procedure of Example 1, 610 mg of (1R,cis) 2,2-dimethyl-3-ethenyl-cyclopropane carboxylic acid and with 800 mg of 1-(2-propynyl)-2-trifluromethyl-3-pyrrole-methanol were reacted to obtain 1.28 g of [2-trifluoromethyl-1-(2-propynyl)-1H-pyrrol-3-yl]-methyl (1R,cis) 2,2-dimethyl-3-ethenyl-cyclopropane carboxylate with a specific rotation of [α]D =+9° (0.2% toluene)
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04737513 |
| Source dataset | uspto-grants-1988_04 |
| ORD ID | ord-57ee305a94de43888892715862017892 |
| Source note | uspto-grants-1988_04 |