反应详情

A mechanically stirred mixture of 1 kg. (7.3 mol.) of d-limonene (7.3 mol.) and sodium carbonate (310.6 g) was cooled to 0°-10° C., and treated with 1.61 kg. (9.1 mol.) 40% peracetic acid by dropwise addition. After the addition was complete, the reaction mixture was stirred for another 45 min., washed with ice water, sodium carbonate, and brine. The oil was dried over magnesium sulfate, and distilled to give recovered limonene (30 g), the cis-epoxide (257 g) and trans-epoxide (296 g), and diepoxide (82 g).

1. additionA mechanically stirred mixture of 1 kg
2. additiontreated with 1.61 kg
3. additionAfter the addition
4. washwashed with ice water, sodium carbonate, and brine
5. dry with materialThe oil was dried over magnesium sulfate
6. distillationdistilled
7. customto give
8. customrecovered limonene (30 g)