HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl Malonate → Diethyl pentafluorobenzylmalonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl Malonate | HCID 7761 | — |
| Reactant | Pentafluorobenzaldehyde | HCID 69558 | — |
| Product | Diethyl pentafluorobenzylmalonate | HCID 88651511 | 69% |
Reaction Steps
9 g of pentafluorobenzaldehyde are condensed on 7 g of diethyl malonate in accordance with the process described in Organic Synthesis vol. III, page 377. 10 g (69%) of diethyl pentafluorobenzylmalonate are obtained which is hydrogenated at ordinary pressure in the presence of palladium on charcoal into diethyl pentafluorobenzylmalonate (92%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04738803 |
| Source dataset | uspto-grants-1988_04 |
| ORD ID | ord-16b1b55501134601a9cbffcc03de0787 |
| Source note | uspto-grants-1988_04 |