HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → 6,11-Dihydroxy-7,8,9,10-tetrahydrotetracene-5,12-dione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Phthaloyl chloride | HCID 6955 | — |
| Reactant | 1,4-Naphthalenediol, 5,6,7,8-tetrahydro- | HCID 83622 | — |
| Product | 6,11-Dihydroxy-7,8,9,10-tetrahydrotetracene-5,12-dione | HCID 419290 | 88% |
Reaction Steps
The method was similar to Example 1 but using 16.4 g (0.1 mols) of 1,4-dihydroxy-5,6,7,8-tetrahydronaphthalene and 20.2 g (0.1 mol) of phthalic acid dichloride. The product was 33.7 g (88% yield) of 6,11-dihydroxy-7,8,9,10-tetrahydro-5,12-naphtacenequinone (9), m.p.=194°-196° C. (EtOH).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04739062 |
| Source dataset | uspto-grants-1988_04 |
| ORD ID | ord-7096ba54468f407297ec2989809e6acc |
| Source note | uspto-grants-1988_04 |