Propyl mercaptan → HCID 20143884, compound

HRID 649346Notes

Reaction equation

HRID 649346 reaction equation
[C:1]([O:6][CH3:7])(=[O:5])/[CH:2]=[CH:3]/[CH3:4].[CH2:8]([SH:11])[CH2:9][CH3:10]>>[CH3:7][O:6][C:1](=[O:5])[CH2:2][CH:3]([S:11][CH2:8][CH2:9][CH3:10])[CH3:4]

Participants

3

Reactant 2

HCID 7848Propyl mercaptanHCID 638132Methyl Crotonate

Product 1

HCID 20143884HCID 20143884, compound

Conditions

Temperature
30 °C

Procedure

Into a 100 cc reaction flask equipped with stirrer, thermometer, reflux condenser and ultra-violet light source are placed 20 grams of methyl crotonate and 15.2 grams of n-propyl mercaptan (0.2 moles of methyl crotonate and 0.2 moles of n-propyl mercaptan). With stirring, the ultra-violet light is turned on and the reaction mass is maintained at a temperature of 30° C. The reaction mass is exposed with stirring to the ultra-violet light at 30° C. for a period of 4 hours. At the end of the 4 hour period, the reaction mass is transferred to a distillation flask and distilled on a micro Vigreux column yielding the following fractions:

Workup

  1. customInto a 100 cc reaction flask
  2. customequipped with stirrer
  3. temperaturethermometer, reflux condenser
  4. stirringwith stirring to the ultra-violet light at 30° C. for a period of 4 hours
  5. customAt the end of the 4 hour period, the reaction mass is transferred to a distillation flask
  6. distillationdistilled on a micro Vigreux column
  7. customyielding the following fractions

Sources & evidence

ORD record
ord-dfb48f702ab64358bc90e8de76a88336
Source dataset
uspto-grants-1988_04
Patent number
US04739105

Reaction notes

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