HRID64938

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID61057

2,6,8-Trimethyl-4-nonanone

C12H24O

HCID70370

2,6-Di-tert-butyl-4-mercaptophenol

C14H22OS

PRODUCTS

生成物

结构：CC(C)CC(C)CC(CC(C)C)(Sc1cc(C(C)(C)C)c(O)c(C(C)(C)C)c1)Sc1cc(C(C)(C)C)c(O)c(C(C)(C)C)c1

HCID13710009

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

The procedure of Example 1 is repeated using 9.22 grams of 2,6,8-trimethylnonan-4-one, 23.84 grams of 2,6-di-tert-butyl-4-mercaptophenol, and 150 ml of methyl alcohol. The product is purified by flask chromatography to give a clear syrup whose proton NMR spectrum is consistent with the desired structure.

WORKUP

后处理

customThe product is purified by flask chromatography
customto give a clear syrup whose proton NMR spectrum

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-075b63a4361245b58aca6358959bfb4f
来源数据集: uspto-grants-1986_09
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04611023
来源说明: uspto-grants-1986_09

反应 SMILES

[CH3:1][CH:2]([CH2:4][C:5](=O)[CH2:6][CH:7]([CH3:12])[CH2:8][CH:9]([CH3:11])[CH3:10])[CH3:3].[C:14]([C:18]1[CH:23]=[C:22]([SH:24])[CH:21]=[C:20]([C:25]([CH3:28])([CH3:27])[CH3:26])[C:19]=1[OH:29])([CH3:17])([CH3:16])[CH3:15]>CO>[C:14]([C:18]1[CH:23]=[C:22]([S:24][C:5]([S:24][C:22]2[CH:21]=[C:20]([C:25]([CH3:26])([CH3:27])[CH3:28])[C:19]([OH:29])=[C:18]([C:14]([CH3:17])([CH3:16])[CH3:15])[CH:23]=2)([CH2:6][CH:7]([CH3:12])[CH2:8][CH:9]([CH3:11])[CH3:10])[CH2:4][CH:2]([CH3:3])[CH3:1])[CH:21]=[C:20]([C:25]([CH3:28])([CH3:27])[CH3:26])[C:19]=1[OH:29])([CH3:17])([CH3:16])[CH3:15]