2-Methoxyethanol → HCID 13750863, compound

HRID 649654Notes

Reaction equation

[OH-].[K+].[CH2:3]1[O:11][C:10]2[C:5](=[CH:6][C:7]([N+:15]([O-:17])=[O:16])=[C:8]([N+:12]([O-:14])=[O:13])[CH:9]=2)[O:4]1.[CH3:18][O:19][CH2:20]CO>>[N+:12]([C:8]1[C:7]([N+:15]([O-:17])=[O:16])=[CH:6][C:5]([OH:4])=[C:10]([O:11][CH2:3][CH2:18][O:19][CH3:20])[CH:9]=1)([O-:14])=[O:13]

Participants

Reactant 3

HCID 80192-Methoxyethanol

HCID 14797Potassium Hydroxide

HCID 6113255,6-Dinitro-1,3-benzodioxole

Product 1

HCID 13750863HCID 13750863, compound

Conditions

Temperature: 45 °C

Procedure

0.2 mol (13.2 g) of potassium hydroxide pellets (85%) is added to 100 ml of ethylene glycol monomethyl ether which has been heated beforehand to 45° C. 0.1 mol (21.2 g) of 4,5-methylenedioxy-1,2-dinitrobenzene, prepared according to Example 1, is added to this solution in the course of 5 minutes. The heating is maintained for 1 hour.

Workup

additionis added to this solution in the course of 5 minutes
temperatureThe heating is maintained for 1 hour

Sources & evidence

ORD record: ord-ee54b5a10fe04c27bca06a41e496bb9c
Source dataset: uspto-grants-1988_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04740622

Reaction notes

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