Butylamine → HCID 13750865, compound

HRID 649656Notes

Reaction equation

HRID 649656 reaction equation
[CH2:1]([NH2:5])[CH2:2][CH2:3][CH3:4].[N+:6]([C:9]1[C:14]([N+]([O-])=O)=[CH:13][C:12]([OH:18])=[C:11]([O:19][CH3:20])[CH:10]=1)([O-:8])=[O:7]>O>[CH2:1]([NH:5][C:14]1[C:9]([N+:6]([O-:8])=[O:7])=[CH:10][C:11]([O:19][CH3:20])=[C:12]([OH:18])[CH:13]=1)[CH2:2][CH2:3][CH3:4]

Participants

4

Reactant 2

HCID 8007ButylamineHCID 184586Phenol, 2-methoxy-4,5-dinitro-

Product 1

HCID 13750865HCID 13750865, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture consisting of 80 ml of n-butylamine, 10 ml of water and 0.1 ml (21.4 g) of 4,5-dinitro-2-methoxyphenol, prepared in Example 2, is heated under reflux. After 4 hours' heating, the reaction mixture is diluted with 800 g of ice-cold water; the expected product precipitates. After being drained and dried, it is taken up in 300 ml of dilute caustic soda and precipitated by adding acetic acid.

Workup

  1. customprepared in Example 2
  2. temperatureis heated
  3. temperatureunder reflux
  4. temperatureAfter 4 hours' heating
  5. customthe expected product precipitates
  6. customdried
  7. customprecipitated
  8. additionby adding acetic acid

Sources & evidence

ORD record
ord-fae70d0835c64a0a9dd720a271d8ad71
Source dataset
uspto-grants-1988_04
Patent number
US04740622

Reaction notes

Loading…