1-Fluoro-2-nitrobenzene → HCID 18422289, compound

HRID 649903Notes

Reaction equation

HRID 649903 reaction equation
[NH2:1][C:2]1[S:6][C:5]2[CH:7]=[CH:8][C:9]([CH3:11])=[CH:10][C:4]=2[C:3]=1[C:12]([O:14][CH3:15])=[O:13].F[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=1[N+:23]([O-:25])=[O:24]>CS(C)=O>[N+:23]([C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][C:17]=1[NH:1][C:2]1[S:6][C:5]2[CH:7]=[CH:8][C:9]([CH3:11])=[CH:10][C:4]=2[C:3]=1[C:12]([O:14][CH3:15])=[O:13])([O-:25])=[O:24]

Participants

4

Reactant 2

HCID 738951-Fluoro-2-nitrobenzeneHCID 18422199HCID 18422199, compound

Product 1

HCID 18422289HCID 18422289, compound

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

In the same manner as in Starting Material Synthesis Example 4 and using methyl 2-amino-5-methylbenzo[b]thiophene-3-carboxylate, 2-fluoronitrobenzene and dimethyl sulfoxide, methyl 2-(2-nitroanilino)-5-methylbenzo[b]thiophene-3-carboxylate was obtained.

Workup

  1. customMaterial Synthesis Example 4

Sources & evidence

ORD record
ord-20d5b06651954b2ca665204e3bd2857c
Source dataset
uspto-grants-2001_08
Patent number
US06271225B1

Reaction notes

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