HuagongsheHuagongshe Chemistry Print Report · For research reference only
Isobutylene oxide → 3-Butyl-5,5-dimethyl-2-propyl-1,3-oxazolidine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Isobutylene oxide | HCID 11208 | — |
| Reactant | N-Butylidenebutylamine | HCID 94840 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 3-Butyl-5,5-dimethyl-2-propyl-1,3-oxazolidine | HCID 10198104 | 53% |
Reaction Steps
A mixture of 1 mmol of N-butylidenebutylamine, 2 mmol of 1,2-epoxy-2-methylpropane, 0.05 mmol of Cp*2Sm(THF)2, and 1 ml of tetrahydrofuran was stirred at room temperature for 5 hours. Products in a reaction mixture were isolated through column chromatography to yield 3-butyl-5,5-dimethyl-2-propyl-1,3-oxazolidine in yield of 53%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06271387B1 |
| Source dataset | uspto-grants-2001_08 |
| ORD ID | ord-bc4876b4c7e448fa93ee94167222db60 |
| Source note | uspto-grants-2001_08 |