HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl Acetate → HCID 21712803, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl Acetate | HCID 8857 | — |
| Reactant | HCID 21712665 | HCID 21712665 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 21712803 | HCID 21712803 | 95.1% |
Reaction Steps
A mixture of 6-ethoxycarbonyl-6,7-dihydrobenzo[b]thiophene (1.00 g), 10% palladium on carbon (2.16 g), AcOEt (30 ml) and MeOH (10 ml) was stirred at r.t. under hydrogen atmosphere for 4 hours. After removal of insoluble solids, the filtrate was concentrated in vacuo to give 6-ethoxycarbonyl-4,5,6,7-tetrahydrobenzo[b]thiophene (0.96 g) as an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06274619B1 |
| Source dataset | uspto-grants-2001_08 |
| ORD ID | ord-a61f71e9b3db48b9840c301b0ce312a5 |
| Source note | uspto-grants-2001_08 |