HRID650699

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC(=O)O[C@H]1CC[C@@]2(C)C(=CC(=O)[C@@H]3[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]32)C1

HCID9798229

未命名化合物

2 次

PRODUCTS

生成物

结构：C[C@]12CC[C@H](O)CC1=CC(=O)[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12

HCID193313

7-Ketodehydroepiandrosterone

C19H26O3

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID21880519

未命名化合物

PROCEDURE

实验过程

The last remains of the product (3) from the mother liquor were obtained by column chromatography of the mother liquor (adsorbed on silica gel) on a small column of silica gel (80-200 mesh) utilizing hexane-acetone (85:15) as eluent. An additional 0.15 gm of 7-oxo-DHEA-Ac (3) was obtained. Total yield 1.75 gm, 56.5% (based on 90% conversion), melting point 185-186° C.