Carbon Disulfide → 2-Phenylethyl (1RS, 3RS)-cis-3-hydroxymethyl-1-methyl-1,2,3,4-tetrahydro-beta-carboline-2-carbodithioate

Beteiligte Stoffe

Reaktionsschritte

In the same manner as described in Example 34 by using (1RS, 3RS)-cis-3-hydroxymethyl-1-methyl-1,2,3,4-tetrahydro-β-carboline (1.08 g), triethylamine (0.7 ml), CS2 (0.3 ml), 2-phenylethyl bromide (0.93 g) and dimethylsulfoxide (5 ml), there is prepared the title compound (1.88 g, 95%) as pale yellow powder, NMR (CDCl3, δ): 3.65 (b, t, J=6.0 Hz, 2H, ##STR24## Mass m/e: 396 (M+), 258 (M+ -- ##STR25##

Herkunft & Nachweise