Tridecylsilane; → HCID 4559047, compound

HRID 651269Notes

Reaction equation

HRID 651269 reaction equation
[SiH:1]([CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31])([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[Si:32]([CH:63]=[CH2:64])([CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][CH2:59][CH2:60][CH2:61][CH3:62])([CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH3:52])[CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH3:42]>>[Si:1]([CH2:64][CH2:63][Si:32]([CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH3:52])([CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH3:42])[CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][CH2:59][CH2:60][CH2:61][CH3:62])([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])([CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

Participants

3

Reactant 2

HCID 4168115Tridecylsilane;HCID 131722834HCID 131722834, compound

Product 1

HCID 4559047HCID 4559047, compoundYield 94%

Procedure

The reaction was carried out in a similar manner as described in Example I. A mixture of (n-C10H21)3SiH (25.0 g, 55.3 mmole), (n-C10H21)3SiCH═CH2 (26.4 g, 55.3 mmole) and Pt(acetylacetonate)2 (22 mg, 5.53×10−2 mmole) was placed in the flask. The reaction mixture was stirred at room temperature for two days and then at ˜40° C. for another two days. The product was purified by column chromatography as described in Example I. After removal of the solvent, a crude product was obtained. The crude product was distilled to remove the low boiling components at <230° C./5×10−5 mmHg and yielded the desired product (n-C10H21)3SiCH2CH2Si(n-C10H21)3 (48.4 g, colorless liquid, 94 percent yield). The infrared spectrum and mass spectra data were consistent with the expected structure. In the analysis for C62H130Si2, the amount calculated was: C, 79.91; H, 14.06; Si, 6.03 percent, while the amount found was: C, 80.12; H, 14.15; Si, 5.92 percent.

Workup

  1. waitat ˜40° C. for another two days
  2. customThe product was purified by column chromatography
  3. customAfter removal of the solvent
  4. customa crude product was obtained
  5. distillationThe crude product was distilled
  6. customto remove the low boiling components at <230° C./5×10−5 mmHg

Sources & evidence

ORD record
ord-b217a4c8fbe043a5b7055245ba9e588e
Source dataset
uspto-grants-2001_08
Patent number
US06278011B1

Reaction notes

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