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HRID651950

反应详情

EQUATION

反应方程式

HRID 651950 的结构方程式

REACTANTS

反应物

2
结构：C[C@H](CCCC(C)(C)O)[C@H]1CC[C@H]2[C@@H]3C=CC4=CC(=O)[C@@H]5O[C@@H]5[C@]4(C)[C@H]3CC[C@]12C
HCID13911126

未命名化合物

结构：CC(=O)OC(C)=O.c1ccncc1
HCID22348678

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)CC(=O)CC(=O)O
HCID5459844

Hexanoic acid, 3,5-dioxo-

C6H8O4

PROCEDURE

实验过程

The cholest-5-ene from Example 4 (c) was acetylated with acetic anhydride/pyridine to yield the triacetate which was subjected to bromination with dibromodimethylhydantoin followed by dehydrobromination with trimethylphosphite according to the procedure of Example 3 (b) to yield, after chromatography on silver nitrate impregnated silica gel, 1α,3β,25-triacetoxycholesta-5,7-diene (m.p. 96°-101°; αD -24° in CHCl3 ; λmaxEt2O 262 (7,900), 271 (11,500), 282 (12,400), 294 (7,300) nm.