Nitric Acid → HCID 86741576, compound

HRID 652391Notes

Reaction equation

HRID 652391 reaction equation
[CH2:1]([NH2:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N+:9]([O-:12])([OH:11])=[O:10]>>[N+:9]([O-:12])([OH:11])=[O:10].[N+:9]([NH:8][CH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)([O-:11])=[O:10]

Participants

3

Reactant 2

HCID 944Nitric AcidHCID 7504Benzylamine

Product 1

HCID 86741576HCID 86741576, compoundYield 118%

Procedure

At a temperature of not higher than 0° C., 107 grams (1 mole) of benzylamine was dropped into 643 grams (10 moles) of 98% nitric acid over a period of 5 hours. After dropping was completed, the reaction was continued at 20°-25° C. for 3 hours with stirring. The resultant reaction mixture was poured into 750 grams of ice water to filter separated crystals, which were washed with an aqueous sodium chloride solution to obtain 254 grams of wet nitrobenzylamine nitrate crystals having a solid content of 61%.

Workup

  1. customThe resultant reaction mixture
  2. filtrationto filter
  3. customseparated crystals, which
  4. washwere washed with an aqueous sodium chloride solution

Sources & evidence

ORD record
ord-3e01a3e0c0004547b6ca0119946c008b
Source dataset
uspto-grants-1987_06
Patent number
US04671890

Reaction notes

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