HuagongsheHuagongshe Chemistry Print Report · For research reference only
Nitric Acid → 2-n-dodecyl-6-hydroxy-7-nitro-2H-1,4-benzoxazin-3-(4H)-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Nitric Acid | HCID 944 | — |
| Reactant | 2-n-dodecyl-6-hydroxy-2H-1,4-benzoxazin-3-(4H)-one | HCID 21298681 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 2-n-dodecyl-6-hydroxy-7-nitro-2H-1,4-benzoxazin-3-(4H)-one | HCID 21298686 | — |
Reaction Steps
Fumic nitric acid (δ1.52, 1.4 ml, 0.0336 mole) in acetic acid (16 ml) was added dropwise under stirring at 15° C. to 2-n-dodecyl-6-hydroxy-2H-1,4-benzoxazin-3-(4H)-one (11.2 g, 0.0336 mole) in acetic acid. The 2-n-dodecyl-6-hydroxy-2H-1,4-benzoxazin-3-(4H)-one (5.6 g, 44%) separated as orange prisms and was used as such.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04672013 |
| Source dataset | uspto-grants-1987_06 |
| ORD ID | ord-6c9a469c8b5749f5bd0e874bdb81016f |
| Source note | uspto-grants-1987_06 |