Formic Acid → HCID 178481199, compound

HRID 653051Notes

Reaction equation

HRID 653051 reaction equation
[CH3:1][NH:2][C:3](=[S:12])[NH:4][NH:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.[CH:13](O)=O>>[CH3:1][N:2]1[CH:13]=[N+:5]([C:6]2[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=2)[N:4]=[C:3]1[S-:12]

Participants

3

Reactant 2

HCID 284Formic AcidHCID 4405145ST50547281

Product 1

HCID 178481199HCID 178481199, compound

Procedure

To 150 ml of formic acid was added 18.1 g of 4-methyl-1-phenylthiosemicarbazide obtained in the above process and the mixture was heat-refluxed for 20 hours. After cooling the reaction mixture and crystals thus formed were collected by filtration and recrystallized from methanol to provide mesoionic 4-methyl-1-phenyl1,2,4-triazolium-3-thiolate as light yellow crystals.

Workup

  1. customobtained in the above process
  2. temperaturethe mixture was heat-refluxed for 20 hours
  3. temperatureAfter cooling the reaction mixture and crystals
  4. customthus formed
  5. filtrationwere collected by filtration
  6. customrecrystallized from methanol

Sources & evidence

ORD record
ord-17d009a65a594d429f9973265b8c8881
Source dataset
uspto-grants-1987_06
Patent number
US04675276

Reaction notes

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