HuagongsheHuagongshe Chemistry Print Report · For research reference only
Malononitrile → 1,1-Dicyanocyclopentane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Malononitrile | HCID 8010 | — |
| Reactant | 1,4-Dibromobutane | HCID 8056 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | 1,1-Dicyanocyclopentane | HCID 15172035 | 53.3% |
Reaction Steps
A mixture of 43.19 g of 1,4-dibromobutane, 13.2 g of malononitrile, 55.3 g of potassium carbonate and 1 liter of acetonitrile was refluxed for 42 hours, filtered while hot and evaporated to dryness giving a dark oil. This oil was vacuum distilled, giving 12.8 g 1,1-cyclopentanedicarbonitrile.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04675336 |
| Source dataset | uspto-grants-1987_06 |
| ORD ID | ord-541c58403ec745568671923c46d34e6e |
| Source note | uspto-grants-1987_06 |