HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Cyclohexene-1-carboxylic acid → HCID 20195502, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Cyclohexene-1-carboxylic acid | HCID 20903 | — |
| Reactant | Nitrogen oxide (N2O4) | HCID 25352 | — |
| Reactant | HCID 20195519 | HCID 20195519 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | HCID 20195502 | HCID 20195502 | — |
Reaction Steps
Starting with 3-(4'-bromomethyl phenyl)-2-bromobenzofuran, nitration with dinitrogen tetraoxide in acetic acid in the presence of cyclohexene-4-carboxylic acid provides 3-(4'bromomethyl phenyl)-2-nitrobenzofuran which is reacted according to the method of Example 1 with N,N'-dimethylaminoethylamine. The product obtained is 3-[4'-(N,N'-dimethylaminoethylaminomethyl)phenyl]-2-nitrobenzofuran having the structure ##STR35##
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04675320 |
| Source dataset | uspto-grants-1987_06 |
| ORD ID | ord-5c4ecb3d9aae436c8448c6f617c098ef |
| Source note | uspto-grants-1987_06 |