Water → HCID 86741638, compound

HRID 653219Notes

Reaction equation

HRID 653219 reaction equation
[P:1]([O-:8])([O:5]CC)[O:2]CC.O.[CH3:10][O:11][CH2:12][CH2:13][CH2:14][NH2:15]>C(O)C>[CH2:12]([P:1](=[O:2])([O-:5])[O-:8])[CH3:13].[CH3:10][O:11][CH2:12][CH2:13][CH2:14][NH3+:15].[CH3:10][O:11][CH2:12][CH2:13][CH2:14][NH3+:15]

Participants

5

Reactant 3

HCID 962WaterHCID 16723-MethoxypropylamineHCID 3780918Diethylphosphite

Product 1

HCID 86741638HCID 86741638, compoundYield 94.3%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent2×

Procedure

A mixture of 13.81 g. of diethyl phosphite, 20 ml. of water and 20 ml. of ethanol is reacted with a mixture of 8.91 g. (0.1 moles) of 3-methoxypropyl amine and 30 ml. of ethanol as described in Example 1. 18.8 g. of 3-methoxypropyl-ammoniumethyl phosphonate are obtained. Yield: 94.3%. nD30 =1,4440

Workup

  1. additionA mixture of 13.81 g

Sources & evidence

ORD record
ord-16c734a23cc0446ebdf3a51965da3b44
Source dataset
uspto-grants-1987_06
Patent number
US04675431

Reaction notes

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