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HRID653477

反应详情

EQUATION

反应方程式

HRID 653477 的结构方程式

REACTANTS

反应物

2
结构：CC(C)(C)CN
HCID79882

2,2-Dimethyl-1-propylamine

C5H13N

结构：O=C1OC(=O)C2(c3ccc([N+](=O)[O-])cc3)CC1C2
HCID54107161

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)CN1C(=O)C2CC(c3ccc([N+](=O)[O-])cc3)(C2)C1=O
HCID20027823

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC(=O)O
溶剂HCID176

Acetic Acid

C2H4O2

PROCEDURE

实验过程

2.4 ml of neopentylamine are added dropwise at room temperature to a suspension of 2.5 g of 1-(4-nitrophenyl)-1,3-cyclobutanedicarboxylic acid anhydride in 6 ml of acetic acid. The mixture is stirred at 120° for 20 hours. After concentration by evaporation, the residue is chromatographed over silica gel with a 2:1 ether/hexane mixture. A fraction is obtained that is identical with the title compound of Example 4b.

WORKUP

后处理

  1. concentrationAfter concentration
  2. customby evaporation
  3. customthe residue is chromatographed over silica gel with a 2:1 ether/hexane mixture
  4. customA fraction is obtained