HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → 1,4-Dichloro-2-(trimethoxy)silyl-2-butene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Diethyl Ether | HCID 3283 | — |
| Reactant | Tetrahydrofuran | HCID 8028 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Trichloro(1,4-dichlorobut-2-en-2-yl)silane | HCID 53421800 | — |
| Product | 1,4-Dichloro-2-(trimethoxy)silyl-2-butene | HCID 54410263 | 80% |
Reaction Steps
Seven milliliters of a THF solution of 14.2 g (55 mmols) of 1,4-dichloro-2-(trichloro)silyl-2-butene was cooled to -10° C., into which was gently dropped a mixed solution of 10 ml (55×3×1.5 mmols) of CH3OH and 34.5 ml (55×3×1.5 mmols) of (C2H5)3N. Subsequently, the mixture was agitated for 1 hour, to which was added 30 ml of dried ether. The resulting (C2H5)3N.HCl was removed by filtration and the solvent was distilled off under a reduced pressure and subjected to vacuum distillation to obtain 10.8 g of 1,4-dichloro-2-(trimethoxy) silyl-2-butene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04677216 |
| Source dataset | uspto-grants-1987_06 |
| ORD ID | ord-d59557c0eae64b5b8b91f8bc78f0b5b0 |
| Source note | uspto-grants-1987_06 |