HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,4-Dichloro-2-butyne → 1,4-Dichloro-2-(dichloromethyl)silyl-2-butene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,4-Dichloro-2-butyne | HCID 13182 | — |
| Reactant | (Dichloromethyl)silane | HCID 57353436 | — |
| Catalyst | Isopropanol | HCID 3776 | — |
| Catalyst | Chloroplatinic acid | HCID 61859 | — |
| Product | 1,4-Dichloro-2-(dichloromethyl)silyl-2-butene | HCID 123615165 | 87.2% |
Reaction Steps
To a mixture of 10 ml (0.106 mol) of 1,4-dichloro-2-butyne and 11.5 ml (0.11 mol) of dichloromethylsilane (boiling point: 41° C.) was added 0.05 ml (4.8 mmol %) of an isopropanol solution of chloroplatinic acid prepared in the same manner as in Example 1, followed by heating under reflux for 1 hour, thereby obtaining 22 g of 1,4-dichloro-2-(dichloromethyl)silyl-2-butene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04677216 |
| Source dataset | uspto-grants-1987_06 |
| ORD ID | ord-db7690e9f4a24cecacaf51e8bc00afc5 |
| Source note | uspto-grants-1987_06 |