HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → 1,4-Dichloro-2-(dimethoxymethyl)silyl-2-butene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Tetrahydrofuran | HCID 8028 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 1,4-Dichloro-2-(dichloromethyl)silyl-2-butene | HCID 123615165 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | 1,4-Dichloro-2-(dimethoxymethyl)silyl-2-butene | HCID 123479824 | 80% |
Reaction Steps
11.5 g (48 mmols) of 1,4-dichloro-2-(dichloromethyl)silyl-2-butene, 1.0 ml of THF, 5.9 ml (48×2×1.5 mmols) of CH3OH, 20 ml (48×2×1.5 mmols) of (C2H5)3N, and 30 ml of (C2H5)2O were used and subjected to vacuum distillation, thereby obtaining 8.8 g of 1,4-dichloro-2-(dimethoxymethyl)silyl-2-butene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04677216 |
| Source dataset | uspto-grants-1987_06 |
| ORD ID | ord-df132fc2d46d403ea3772ff03878e394 |
| Source note | uspto-grants-1987_06 |