Azido(trimethyl)stannane → HCID 178439892, compound

HRID 653649Notes

Reaction equation

HRID 653649 reaction equation
[CH2:1]([C:4]1[N:8]([CH2:9][C:10]2[CH:15]=[CH:14][C:13]([C:16]3[CH:21]=[CH:20][N:19]=[CH:18][C:17]=3[C:22]#[N:23])=[CH:12][CH:11]=2)[C:7]2[CH:24]=[CH:25][CH:26]=[C:27]([CH3:28])[C:6]=2[N:5]=1)[CH2:2][CH3:3].[Sn]([N:33]=[N+:34]=[N-:35])(C)(C)C>C1(C)C=CC=CC=1>[CH2:1]([C:4]1[N:8]([CH2:9][C:10]2[CH:15]=[CH:14][C:13]([C:16]3[CH:21]=[CH:20][N:19]=[CH:18][C:17]=3[C:22]3[NH:35][N:34]=[N:33][N:23]=3)=[CH:12][CH:11]=2)[C:7]2[CH:24]=[CH:25][CH:26]=[C:27]([CH3:28])[C:6]=2[N:5]=1)[CH2:2][CH3:3]

Participants

4

Reactant 2

HCID 5104973Azido(trimethyl)stannaneHCID 19889372HCID 19889372, compound

Product 1

HCID 178439892HCID 178439892, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

The title compound may be prepared by treatment of 2-propyl-4-methyl-1-[4-[3-cyano-4-pyridinyl]phenyl]methylbenzimidazole with one or more equivalents of Me3SnN3 in toluene at reflux over a period of 1-3 days. The title compound may be purified in a manner similar to that stated in Example 1, Step F.

Sources & evidence

ORD record
ord-957318f6546f4fd7b441e37e6b05c0e8
Source dataset
uspto-grants-1992_07
Patent number
US05128327

Reaction notes

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