1-Chloro-1-phenylsiletane → HCID 12597992, compound

Participants

Reaction Steps

A dry 250 ml three neck round bottom flask equipped with a dropping funnel and condenser with nitrogen inlet system. Was placed 4.2 g (23 mmole) 1-chloro-1-phenyl-1-silacyclobutane in 40 ml THF. With stirring, 25 ml (0.1M) vinyl magnesium bromide (in THF) was added dropwise. The mixture was stirred for additional 6 h. Work up, the mixture was distilled to collect 2.8 g 82°-83° C./3.0 mmHg 70% yield was obtained.

Provenance & Evidence