Ethanolamine → 2-Heneicosyl-4,5-dihydrooxazole

HRID 654280Notes

Reaction equation

HRID 654280 reaction equation
[C:1]([OH:24])(=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22].[CH2:25]([CH2:27][NH2:28])O>CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-].[Ti+4]>[CH2:2]([C:1]1[O:24][CH2:25][CH2:27][N:28]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]

Participants

4

Reactant 2

HCID 700EthanolamineHCID 8215Docosanoic Acid

Product 1

HCID 144734472-Heneicosyl-4,5-dihydrooxazole

Reagents, catalysts & solvents 1

HCID 21801Titanium tetrabutoxideCatalyst

Procedure

Following the procedure of Example 2, behenic acid was reacted with ethanolamine in the presence of titanium tetrabutylate as catalyst to form 2-heneicosyl-2-oxazoline.

Sources & evidence

ORD record
ord-1fcb15caea0941e5b5bee1cc4883c1d8
Source dataset
uspto-grants-1992_07
Patent number
US05130440

Reaction notes

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