1-(Benzyloxy)-2-methoxy-3-nitro-4-(2-nitroethenyl)benzene → HCID 21850161, compound

HRID 654386Notes

Reaction equation

HRID 654386 reaction equation
C(OC1C(OCC)=CC=C([N+]([O-])=O)C=1C=C[N+]([O-])=O)C1C=CC=CC=1.[CH2:26]([O:33][C:34]1[CH:44]=[CH:43][C:37]([CH:38]=[CH:39][N+]([O-])=O)=[C:36]([N+:45]([O-])=O)[C:35]=1[O:48][CH3:49])[C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1>>[CH2:26]([O:33][C:34]1[C:35]([O:48][CH3:49])=[C:36]2[C:37]([CH:38]=[CH:39][NH:45]2)=[CH:43][CH:44]=1)[C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1

Participants

3

Reactant 2

HCID 538975591-(Benzyloxy)-2-methoxy-3-nitro-4-(2-nitroethenyl)benzeneHCID 539721921-Ethoxy-4-nitro-3-(2-nitroethenyl)-2-(phenylmethoxy)benzene

Product 1

HCID 21850161HCID 21850161, compoundYield 75%

Procedure

This compound is obtained according to the operating method described in Example 1c, in which the 2-benzyloxy-3-ethoxy-6,β-dinitrostyrene is replaced with 4-benzyloxy-3-methoxy-2,β-dinitrostyrene. White crystals (yield=75%, m.p.=66°-67° C.) are obtained.

Workup

  1. customThis compound is obtained

Sources & evidence

ORD record
ord-331b125f86fb4935a4908f74c9b1d51b
Source dataset
uspto-grants-1992_07
Patent number
US05131911

Reaction notes

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