HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl Acetate → HCID 15171836, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl Acetate | HCID 8857 | — |
| Reactant | rac-3,4-dihydro-2-ethynyl-2,5,7,8-tetramethyl-2H-1-benzopyran-6ol | HCID 14478563 | — |
| Reactant | 4-(Hydroxymethyl)-2-iodo-6-methoxyphenol | HCID 15171834 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 15171836 | HCID 15171836 | — |
Reaction Steps
This compound was obtained by reacting rac-3,4-dihydro-2-ethynyl-2,5,7,8-tetramethyl-2H-1-benzopyran-6-ol with 3-iodo-4-hydroxy-5-methoxybenzenemethanol [P. Claus et al. Monatsh. Chem. 103, 1178 (1972)] under the conditions described in Example 1. The product was isolated by chromatography over silica gel using 30% (V/V) of ethyl acetate in methylene chloride. Crystallization from ether/hexane yielded colorless crystals with m.p. 160°-163°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05132310 |
| Source dataset | uspto-grants-1992_07 |
| ORD ID | ord-96f15f91bade41f59304ab7497b4fb7f |
| Source note | uspto-grants-1992_07 |