Pyridine → HCID 16687968, compound

HRID 654534Notes

Reaction equation

HRID 654534 reaction equation
[CH3:1][C:2](Cl)([CH3:9])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[N:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1.[F:17][Sb-:18]([F:23])([F:22])([F:21])([F:20])[F:19].[Na+]>CO>[F:17][Sb-:18]([F:23])([F:22])([F:21])([F:20])[F:19].[CH3:1][C:2]([N+:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)([CH3:9])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

Participants

5

Reactant 3

HCID 1049PyridineHCID 70281(1-Chloro-1-methylethyl)benzeneHCID 16689647Sodium hexafluoroantimonate

Product 1

HCID 16687968HCID 16687968, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

4.644 g (0.03 mol) of α,α-dimethylbenzyl chloride and 2.373 g (0.03 mol) of pyridine were reacted in 40 ml of methanol at 40° C. for 3 days. After the reaction, the solvent was evaporated in vacuo and ether-water was added to the residue to extract unreacted reactants in the etherial layer. To the aqueous layer was added 7.7 g (0.03 mol) of sodium hexafluoroantimonate. The resulting crystals were suction filtered, washed and dried to give the title compound.

Workup

  1. customAfter the reaction
  2. customthe solvent was evaporated in vacuo and ether-water
  3. additionwas added to the residue
  4. extractionto extract unreacted reactants in the etherial layer
  5. filtrationfiltered
  6. washwashed
  7. customdried

Sources & evidence

ORD record
ord-1b22a44aef0d43dda0d4773ae0c0d2ea
Source dataset
uspto-grants-1992_07
Patent number
US05132377

Reaction notes

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